#\#CIF_2.0
# Created by the Bilbao Crystallographic Server
# http://www.cryst.ehu.es
# Date: 23/02/2021 

data_5yOhtAoR
_audit_creation_date            2021-02-23
_audit_creation_method          "Bilbao Crystallographic Server"

_audit_creation_date            2021-02-23
_audit_creation_method          "Bilbao Crystallographic Server"

_citation_journal_abbrev        "Angew. Chem. Int. Ed."
_citation_journal_volume        54
_citation_page_first            12074
_citation_page_last             12077
_citation_article_id            .
_citation_year                  2015
_citation_DOI                   10.1002/anie.201506540

loop_
_citation_author_name
"A. M. Arevalo-Lopez"
"G. M. McNally"
"J. P. Attfield"

_atomic_positions_source_database_code_ICSD  195631
_atomic_positions_source_other               .

_transition_temperature  520
_experiment_temperature  150

loop_
_irrep_id
_irrep_dimension
_irrep_small_dimension
_irrep_direction_type
_irrep_action
_irrep_modes_number
_irrep_presence
mGM1+  1  1  .  primary  9   .
mGM2+  1  1  .  primary  9   .

_exptl_crystal_magnetic_properties_details
;
NPD
Non-standard parent setting P2_1/n
Ferrimagnetic
Another phase below 75K
;

_active_magnetic_irreps_details
;
1k magnetic structure
Two 1-dim irreps involved as primary. This means that two order parameters are present. One for the ordering of the Fe and Re moments, and another one with different irrep for the Mn ordering. At 300K, Mn moments are reported to be zero (see #0.541) and a single irrep is involved. However, the article does not report any transition between 300K and the present measurement at 150K, where Mn is reported to be magnetically ordered according to a different irrep.
Below 75K another phase is reported 
;

_parent_space_group.name_H-M_alt  'P 2_1/c'
_parent_space_group.IT_number                       14
_parent_space_group.transform_Pp_abc  'a,b,-a+c;0,0,0'

loop_
_parent_propagation_vector.id
_parent_propagation_vector.kxkykz
k1 [0 0 0]

_parent_space_group.child_transform_Pp_abc  'a,b,c;0,0,0'
_space_group_magn.transform_BNS_Pp_abc  'a,b,c;0,0,0'



_space_group_magn.number_BNS  2.4
_space_group_magn.name_BNS  "P -1"
_cell_length_a             5.1872(2)
_cell_length_b             5.3550(1)
_cell_length_c             7.5706(2)
_cell_angle_alpha          90.00
_cell_angle_beta           90.039(8)
_cell_angle_gamma          90.00

loop_
_space_group_symop_magn_operation.id
_space_group_symop_magn_operation.xyz
1 x,y,z,+1 
2 -x,-y,-z,+1 

loop_
_space_group_symop_magn_centering.id
_space_group_symop_magn_centering.xyz
1 x,y,z,+1 

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Mn1_1 Mn 0.4802(9) 0.5645(7) 0.759(2)
Mn1_2 Mn  0.0198 0.0645 0.741
Fe1_1 Fe 0.50000 0.00000 0.50000
Fe1_2 Fe  0.00000 0.50000 0.00000
Re1_1 Re 0.50000 0.00000 0.00000
Re1_2 Re  0.00000 0.50000 0.50000
O1_1 O 0.320(2) 0.292(1) 0.933(8)
O1_2 O  0.180 0.792 0.567
O2_1 O 0.323(2) 0.331(1) 0.564(1)
O2_2 O  0.177 0.831 0.936
O3_1 O 0.8712(5) 0.4430(5) 0.7752(6)
O3_2 O  0.6288 0.9430 0.7248

loop_
_atom_site_moment.label
_atom_site_moment.crystalaxis_x
_atom_site_moment.crystalaxis_y
_atom_site_moment.crystalaxis_z
_atom_site_moment.symmform
_atom_site_moment.magnitude
Mn1_1 0.00000 0.00000 0.56(5) mx,my,mz     0.56(5)
Mn1_2 0.00000 0.00000 -0.56 mx,my,mz       0.56
Fe1_1 0.00000 0.00000 4.02(6) mx,my,mz     4.02(6
Fe1_2 0.00000 0.00000 4.02 mx,my,mz        4.02
Re1_1 0.00000 0.00000 -0.59(6) mx,my,mz    0.59(6)
Re1_2 0.00000 0.00000 -0.59 mx,my,mz       0.59

