#\#CIF_2.0
# Created by the Bilbao Crystallographic Server
# http://www.cryst.ehu.es
# Date: 06/29/2025 14:03:42
# Corrected entry 0.355. A wrong MSG was assigned in the previous version

data_5yOhtAoR
_audit_creation_date            2025-06-29
_audit_creation_method          "Bilbao Crystallographic Server"

_chemical_name_systematic
;
;
_chemical_name_common                    ?
_chemical_formula_moiety                 ?
_chemical_formula_structural             ?
_chemical_formula_analytical             ?
_chemical_formula_iupac                  ?
_chemical_formula_sum                    "Mn2.85 Ga1.15"
_chemical_formula_weight                 ?
_chemical_melting_point                  ?
_chemical_compound_source                ?
_chemical_absolute_configuration         ?


_citation_journal_abbrev        "Solid State Communications"
_citation_journal_volume        8
_citation_page_first            1653
_citation_page_last             1655
_citation_article_id            .
_citation_year                  1970
_citation_DOI                   10.1016/0038-1098(70)90484-9

loop_
_citation_author_name
"E. Kren"
"G. Kadar"

_temperature_position_structure         .
_temperature_atom_positions             .
_temperature_non-magn_atom_positions    .
_temperature_cell_parameters            .

_atomic_positions_source_database_code_ICSD  198472
_atomic_positions_source_other               .

_transition_temperature     460
_experiment_temperature     300

loop_
_irrep_id
_irrep_dimension
_irrep_small_dimension
_irrep_direction_type
_irrep_action
_irrep_modes_number
_irrep_presence
mGM4+ 1  1  .  primary  1  .
mGM3+ 1  1  .  primary  1  .  

_exptl_crystal_magnetic_properties_details
;
NPD?
Mn moment: 2.4(2)
Mn moment components given non-ignificant digits to yield the reported modulus.
;

_active_magnetic_irreps_details
;
1k magnetic structure
Two 1-dim irreps as primary irreps
Weak FM is reported, but it is inconsistent with the MSG of the structure
;

_parent_space_group.name_H-M_alt  'P 6_3/m m c'
_parent_space_group.IT_number                       194
_parent_space_group.transform_Pp_abc  'a,b,c;0,0,0'

loop_
_parent_propagation_vector.id
_parent_propagation_vector.kxkykz
k1 [0 0 0]

_parent_space_group.child_transform_Pp_abc  'a,b,c;0,0,0'
_space_group_magn.transform_BNS_Pp_abc  'a,b,c;0,0,0'


_space_group_magn.number_BNS  176.147
_space_group_magn.name_BNS  "P 6_3'/m'"
_space_group_magn.point_group_name  "6'/m'"
_space_group_magn.point_group_number  "23.5.86"
_cell_length_a                 5.36300
_cell_length_b                 5.36300
_cell_length_c                 4.32700
_cell_angle_alpha              90.00
_cell_angle_beta               90.00
_cell_angle_gamma              120.00

loop_
_space_group_symop_magn_operation.id
_space_group_symop_magn_operation.xyz
1 x,y,z,+1 
2 -y,x-y,z,+1 
3 -x+y,-x,z,+1 
4 -x,-y,-z,+1 
5 y,-x+y,-z,+1 
6 x-y,x,-z,+1 
7 x-y,x,z+1/2,-1 
8 -x,-y,z+1/2,-1 
9 y,-x+y,z+1/2,-1 
10 -x+y,-x,-z+1/2,-1 
11 x,y,-z+1/2,-1 
12 -y,x-y,-z+1/2,-1 

loop_
_space_group_symop_magn_centering.id
_space_group_symop_magn_centering.xyz
1 x,y,z,+1 

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
Ga1 Ga 0.33333 0.66667 0.25000 1.
Ga2 Ga 0.83333 0.66666 0.25000 0.05
Mn1 Mn 0.83333 0.66666 0.25000 0.95

loop_
_atom_site_moment.label
_atom_site_moment.crystalaxis_x
_atom_site_moment.crystalaxis_y
_atom_site_moment.crystalaxis_z
_atom_site_moment.symmform
_atom_site_moment.magnitude
_atom_site_moment.spherical_azimuthal
_atom_site_moment.spherical_polar
Mn1 2.68 1.96 0.0 mx,my,0 2.4(2) ? ?

